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Peptides need refrigeration because they are fragile molecules that break down over time, and cold dramatically slows that breakdown.
This post-translational modification is now recognised as a major mechanism of redox-regulated cell signalling, controlling the activity of transcription factors, kinases, phosphatases, and metabolic enzymes in response to the intracellular redox environment
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Current Neuropharmacology, 16(5), 566-583
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